Sunlight photodepolymerization of transient polymers

The study and development of transient devices is an emerging field where the disposal of a device after use is desired to avoid reverse engineering and minimize the environmental impact. Polyaldehydes with phototriggers have been investigated because the radiation wavelength can be adjusted to meet the transient application. Polynuclear aromatic hydrocarbons (PAHs) were used as the optical sensitizer for photoacid generators (PAGs). Photoinduced electron transfer (PET) with an iodonium-based PAG was used to expand the spectral sensitivity range. Anthracene, tetracene, and pentacene derivatives were synthesized with appended phenylethynyl groups to improve the solubility of the sensitizer and adjust the absorption wavelength. Sensitization of the iodonium-based PAG with the PAH derivatives was found to have thermodynamically favorable PET reactions for depolymerization of poly(propylene carbonate) and poly(phthalaldehyde) (PPHA). The Rehm–Weller equation and Stern–Volmer analysis were used to study the electron transfer and the fluorescence quenching rates of the PAHs with the iodonium salts, respectively. The photosensitivity, efficiency, and byproducts of the PET reactions in the decomposable polymer films are reported. A rapid photoreaction is reported for the depolymerization of PPHA exposed to a sunlight dose of <6 J cm⁻² (i.e., 1 min of direct sunlight) with a pentacene-based sensitizer. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47141.     

Intermolecular interactions in phytochemical model systems studied by NMR diffusion measurements

Novel functional foods, such as tomato juice with soy, represent a new strategy to increase consumption of health promoting ingredients and phytochemicals. Interactions between soy protein, isoflavones, and tomato carotenoids could impact the bioaccessibility and bioavailability of individual phytochemicals. The primary objective of this study was to assess possible interactions between daidzein and daidzin, soy protein and carotenoids using proton one-dimensional and two-dimensional pulsed field gradient nuclear magnetic resonance spectroscopy experiments.     

The paradox of oil reserve forecasts: The political implications of predicting oil reserves and oil consumption

In the light of the outstanding importance of hydrocarbons for global energy, the controversy over peak oil has become both pressing and emotionally charged. Two conflicting parties – alarmists and optimists – hold irreconcilable positions. The shaping of the future energy policy is presently based on modeling results and geological considerations only. We show that the existing predictions of the energy crisis are increasingly mixed-up with value-judgments. The value analysis of those forecasts allows us to suggest that at least part of the estimations are implicit reflections of predictors’ ends and values, and do not demonstrate a real ability to anticipate future conditions. Paradoxically, the question of oil reserves depletion is better understood when predictions are viewed as an instrument to impose the predictors’ values and intervene in the currently bustling oil market. The intervention in the oil prices may occur in either direction becoming a tool to justify values rather than an instrument for the acquisition of knowledge.     

Assessment of strategic self-regulation in traumatic brain injury: Its relationship to injury severity and psychosocial outcome.

Standard neuropsychological tests administered in a constrained and artificial laboratory environment are often insensitive to the real-life deficits faced by patients with traumatic brain injury (TBI). The Revised Strategy Application Test (R-SAT) creates an unstructured environment in the laboratory in which environmental cues and internal habits oppose the most efficient strategy, thus mimicking the real-life situations that are problematic for patients with TBI. In this study, R-SAT performance was related both to severity of TBI (i.e., depth of coma) sustained 2–3 years earlier and to quality of life outcome as assessed by the Sickness Impact Profile. This relationship held after accounting for variance attributable to TBI-related slowing and inattention. These findings support the validity of the R-SAT and suggest that behavioral correlates of quality of life outcome in TBI can be assessed in the laboratory with unstructured tasks. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Constrained Codes as Networks of Relations

We address the well-known problem of determining the capacity of constrained coding systems. While the one-dimensional case is well understood to the extent that there are techniques for rigorously deriving the exact capacity, in contrast, computing the exact capacity of a two-dimensional constrained coding system is still an elusive research challenge. The only known exception in the two-dimensional case is an exact (however, not rigorous) solution to the -run-length limited (RLL) system on the hexagonal lattice. Furthermore, only exponential-time algorithms are known for the related problem of counting the exact number of constrained two-dimensional information arrays. We present the first known rigorous technique that yields an exact capacity of a two-dimensional constrained coding system. In addition, we devise an efficient (polynomial time) algorithm for counting the exact number of constrained arrays of any given size. Our approach is a composition of a number of ideas and techniques: describing the capacity problem as a solution to a counting problem in networks of relations, graph-theoretic tools originally developed in the field of statistical mechanics, techniques for efficiently simulating quantum circuits, as well as ideas from the theory related to the spectral distribution of Toeplitz matrices. Using our technique, we derive a closed-form solution to the capacity related to the Path-Cover constraint in a two-dimensional triangular array (the resulting calculated capacity is ). Path-Cover is a generalization of the well known one-dimensional -RLL constraint for which the capacity is known to be .     

On the existence and synthesis of multifinger positive grips

We study the criteria under which an object can be gripped by a multifingered dexterous hand, assuming no static friction between the object and the fingers; such grips are calledpositive grips. We study three cases in detail: (i) the body is at equilibrium, (ii) the body is under some constant external force/torque, and (iii) the body is under a varying external force/torque. In each case we obtain tight bounds on the number of fingers needed to obtain grip.We also present efficient algorithms to synthesize such positive grips for bounded polyhedral/polygonal objects; the number of fingers employed in the grips synthesized by our algorithms match the above bounds. The algorithms run in time linear in the number of faces/sides.The paper may be of independent interest for its presentation of algorithms arising in the study of positive linear spaces.Work on this paper has been supported by Office of Naval Research Grant N00014-82-K.-0381, National Science Foundation Grant No. NSF-DCR-83-20085, and by grants from the Digital Equipment Corporation, and the IBM Corporation.     

Electing a leader in a ring with link failures

Summary We investigate the message complexity of electing a leader in a ring of asynchronous processors. Our work deviates from the previous works on electing a leader in that we consider the effect of link failures. A link is said to fail if some message sent through it never reaches its destination. We distinguish the case where n is known from the case n unknown. Our main result is a O(n · log n) algorithm for electing a leader on a n-processor ring (the case n is known).     

Crack speed relations inferred from large SEN specimens of A533B steel

A relationship between instantaneous crack tip velocity ( ), dynamic stress intensity factor (K_I, and temperature (T) for A533B steel is estimated using dynamic crack position vs time data measured in a series of very large scale crack arrest tests. The corresponding dynamic stress intensity vs time history and the dynamic arrest toughness for each test are obtained from generation mode elastodynamic analyses based on cubic polynomial fits to the discrete crack position data points. Application mode elastodynamic analytical predictions based on the proposed relationship are within 7% of experimentally measured arrest crack lengths and within 50% of measured arrest times. These predictions represent significant improvements over results obtained using previous preliminary estimates of the relation for A533B. The influence of nonlinear material behavior on the results is also evaluated.